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UPSC Prelims 2025Question 45Science & Technology

Consider the following substances
I. Ethanol
II. Nitroglycerine
III. Urea
Coal gasification technology can be used in the production of how many of them?

Options

  1. (a)Only one
  2. (b)Only two
  3. (c)All the three
  4. (d)None
Correct answer: b
Decision rule

Coal gasification yields syngas, so anything reachable from carbon monoxide and hydrogen qualifies; products needing fats or glycerol do not.

Explanation

Correct Answer:

(b) Only two


Explanation of the Correct Answer:

Coal gasification enables the production of chemicals through downstream synthesis using syngas (CO + H₂). Let’s assess each substance:


  • I. Ethanol
    • Yes, ethanol can be produced via coal gasification, though not directly.
    • Syngas produced from gasified coal can be converted to ethanol using catalysts (via syngas-to-alcohol synthesis, e.g., via the Fischer–Tropsch or other catalytic processes).
  • II. Nitroglycerine
    • No, nitroglycerine is made from glycerol and nitric acid, not from coal-derived products.
    • Glycerol comes from biological sources (fats/oils), and nitric acid is derived from ammonia, which can be made from syngas—but coal gasification does not directly produce or contribute significantly to nitroglycerine synthesis.
  • III. Urea
    • Yes, urea is made by combining ammonia (produced from syngas via the Haber-Bosch process) with carbon dioxide.
    • Since coal gasification can be used to produce ammonia and CO₂, it indirectly enables urea production.
Coal gasification is a process that converts coal into a synthetic gas (syngas) composed primarily of carbon monoxide (CO) and hydrogen (H2)

Why Other Options Are Incorrect:

  • (a) Only one – Incorrect: Ethanol and Urea can both be produced.
  • (c) All the three – Incorrect: Nitroglycerine cannot be made from coal gasification products.
  • (d) None – Incorrect: Two of the three substances can be produced.

Relevant Supplementary Information

Table: Evaluation of Substances and Coal Gasification

SubstanceCoal Gasification as Source?Explanation
EthanolYes (indirect via syngas)Syngas → alcohol synthesis
NitroglycerineNoRequires glycerol and nitric acid (non-coal-based inputs)
UreaYes (via ammonia from syngas)Ammonia + CO₂ → Urea; ammonia comes from syngas (Haber-Bosch process)

Related Concepts:

  • Coal Gasification: Converts coal into syngas (CO + H₂ + CO₂), used in chemical synthesis and energy generation.
  • Fischer–Tropsch Process: Converts syngas into liquid fuels or chemicals like ethanol.
  • Haber-Bosch Process: Converts hydrogen (from syngas) and nitrogen into ammonia for fertilizers.

Current Relevance:

  • India is investing in coal-to-chemicals and coal-to-urea projects to reduce fertilizer import dependence.
  • Clean coal technologies are being promoted to minimize emissions while utilizing coal reserves for value-added outputs.
  • The National Coal Gasification Mission aims to gasify 100 MT of coal by 2030.

Table: Coal Gasification and Production of Selected Substances

SubstanceCan be Produced from Coal Gasification?How It Is ProducedKey Inputs from Coal GasificationRemarks
EthanolYes (indirectly)Via syngas-to-alcohol synthesis using catalytic processes (e.g., Fischer–Tropsch)Syngas (CO + H₂)Emerging technology; not widely commercial yet
NitroglycerineNoMade by nitrating glycerol with nitric and sulfuric acidNot related to syngas or coal gasificationGlycerol is derived from fats/oils, not coal
UreaYes (indirectly)By reacting ammonia (from syngas) with CO₂H₂ (for ammonia) and CO₂ from coal gasificationCommercially done in coal-based urea plants

Key Chemical Pathways Involved

ProcessReaction SummaryCoal Gasification Link
Coal GasificationC + H₂O + O₂ → CO + H₂ (syngas)Base reaction to derive chemical feedstocks
Fischer–Tropsch (Ethanol)CO + H₂ → Ethanol + other alcohols (via catalysts)Converts syngas to liquid fuels or chemicals
Haber-Bosch (Urea Precursor)N₂ + 3H₂ → 2NH₃H₂ from syngas is used to make ammonia
Urea Synthesis2NH₃ + CO₂ → (NH₂)₂CO + H₂ONH₃ and CO₂ both can be derived from coal gasification
Nitroglycerine SynthesisC₃H₅(OH)₃ + 3HNO₃ → C₃H₅N₃O₉ + 3H₂O (nitration of glycerol)No connection to coal gasification

Related Concepts

ConceptExplanation
SyngasA gas mixture of carbon monoxide and hydrogen; key output of coal gasification
Fischer–Tropsch ProcessConverts syngas into alcohols, hydrocarbons, etc., using catalysts
Haber-Bosch ProcessIndustrial method for producing ammonia from nitrogen and hydrogen
Coal-to-ChemicalsStrategic use of coal for producing fertilizers, fuels, and solvents


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