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Composition and Structure of Atmosphere
Start here: why this chapter matters
This short chapter opens Unit IV, ‘Climate’. Everything you study next — sunlight and temperature (Chapter 8), pressure and winds (Chapter 9), humidity, clouds and rain (Chapter 10) and climate change (Chapter 11) — happens inside the atmosphere described here, mostly in its lowest layer. Learn its gases and layers well: they are the vocabulary of the whole unit.
- Opens Unit IV (Climate) and leads into Chapters 8–11.
- Links to environment topics: greenhouse gases, ozone depletion, air pollution, and to space technology (radio communication, satellites).
- UPSC: Prelims has asked the order of layers (1984, 1998), the ozone layer (1982, 1986, 1987), the ionosphere and radio waves (1996, 2011), why jets fly in the lower stratosphere (2011), water vapour (2003, 2024), troposphere thickness (2004, 2024) and dust (2025). Mains GS1 asked why the troposphere is so significant for weather (2022).
| Word | What it means here |
|---|---|
| Atmosphere | The envelope of gases, water vapour and dust round the earth |
| Insolation / solar radiation | Energy coming in from the sun (mostly short-wave) |
| Terrestrial radiation | Heat given out by the earth (long-wave, infrared) |
| Transparent / opaque | Lets radiation pass / blocks or absorbs it |
| Ultraviolet (UV) rays | Harmful high-energy rays in sunlight |
| Hygroscopic nuclei | Tiny particles (dust, salt) that attract water vapour to condense on them |
| Ion | An electrically charged particle |
| Lapse rate | The rate at which temperature falls with height |
| -pause | The boundary at the top of a layer (tropopause, stratopause, mesopause) |
At a glance — the six ideas to carry away
- 99% of the atmosphere's mass lies within 32 km; oxygen is negligible by 120 km; CO₂ and water vapour reach 90 km.
- CO₂: transparent to incoming sunlight, opaque to outgoing heat → greenhouse effect; rising with fossil-fuel burning.
- Ozone (10–50 km) absorbs ultraviolet rays; water vapour (≤ 4%) is a heat blanket; dust and salt are cloud nuclei.
- Five layers by temperature: troposphere → stratosphere → mesosphere → thermosphere (ionosphere) → exosphere.
- Troposphere: all weather; ~8 km at the poles, ~18 km at the equator; temperature falls 1°C per 165 m.
- Ionosphere (80–400 km) reflects radio waves; geographers care most about the first two layers.
1. What air is made of: the gases
The atmosphere is a mixture of gases, water vapour and dust particles that envelops the earth. It contains life-giving gases — oxygen for humans and animals, carbon dioxide for plants. Air is part of the earth's mass: 99% of the atmosphere's total mass lies within 32 km of the surface. Air is colourless and odourless and is felt only when it blows as wind. The proportions change with height: oxygen is almost negligible at 120 km, and carbon dioxide and water vapour are found only up to 90 km.
| Gas | What NCERT says | Why it matters |
|---|---|---|
| Carbon dioxide | Meteorologically very important. Transparent to incoming solar radiation but opaque to outgoing terrestrial radiation; absorbs part of the earth's radiation and sends part back to the surface. Its volume has been rising in recent decades, mainly from burning fossil fuels, which has raised air temperature | Largely responsible for the greenhouse effect; other gases' volumes are constant |
| Ozone | Found between 10 and 50 km; acts as a filter, absorbing ultraviolet rays from the sun | Without it, harmful UV would reach the surface |
| Oxygen | Negligible by 120 km | Breathing for humans and animals |
2. Water vapour and dust particles
Water vapour is a variable gas. It decreases with altitude and from the equator towards the poles. In the warm, wet tropics it may be about 4% of the air by volume; in dry, cold deserts and polar regions less than 1%. It absorbs part of the incoming insolation and keeps the earth's radiated heat, acting like a blanket so the earth gets neither too hot nor too cold. It also affects the stability and instability of air.
Dust particles come from many sources: sea salt, fine soil, smoke-soot, ash, pollen, dust and disintegrated meteors. They are concentrated in the lower layers, though convection can carry them high. Concentration is higher in subtropical and temperate regions because of dry winds, than in equatorial and polar regions. Dust and salt particles act as hygroscopic nuclei around which water vapour condenses to form clouds.
3. Structure of the atmosphere: five layers
The atmosphere has layers of different density and temperature. Density is highest near the surface and decreases with height. By temperature, there are five layers: troposphere, stratosphere, mesosphere, thermosphere and exosphere.
- A graph: altitude (km) up the side, temperature (°C) from −100 to +20 along the bottom. One zig-zag line shows how temperature changes with height.
- Read the zig-zag: temperature falls through the troposphere from about +15°C to about −57°C; stays constant for a while above the tropopause, then rises through the stratosphere to about 0°C at the stratopause (50 km); falls again through the mesosphere to about −90°C at the mesopause (80 km); then rises steeply in the thermosphere, dashing on into the exosphere above about 400 km.
- Information only in the figure: the stratopause (the text never names it), and that temperature increases with height in the stratosphere — the text only hints at it with ‘once again, temperature starts decreasing’ in the mesosphere.
- The altitude axis is not to scale: 0, 10, 50, 80 and 400 km are spaced so the upper layers fit — the gap from 80 to 400 km is squeezed.
- The figure's numbers are for an average/mid-latitude atmosphere: its tropopause (~−57°C at about 11 km) and mesopause (~−90°C) differ from the text's −80°C (equator) / −45°C (poles) and −100°C. The figure labels the layer above 80 km ‘Thermosphere’; the text describes it as the ‘ionosphere’.
| Layer | Height (NCERT) | Temperature with height | Key facts |
|---|---|---|---|
| Troposphere | Average 13 km; ~8 km at poles, ~18 km at equator | Falls, 1°C per 165 m | Dust and water vapour; all weather and climate changes; most important for biological activity |
| Tropopause | Top of the troposphere | Nearly constant: about −80°C over the equator, −45°C over the poles | Boundary zone |
| Stratosphere | Up to 50 km | Rises (Figure 7.1) | Ozone layer absorbs UV and shields life |
| Mesosphere | Up to 80 km | Falls again, to about −100°C at 80 km | Top = mesopause |
| Thermosphere / ionosphere | 80–400 km | Rises with height | Ions reflect radio waves back to earth |
| Exosphere | The uppermost layer | — | Extremely rarefied; very little known; merges with outer space |
4. The troposphere and tropopause
The troposphere is the lowest layer. Its average height is 13 km — about 8 km near the poles and 18 km at the equator. It is thickest at the equator because heat is carried to great heights by strong convection currents. It holds the dust particles and water vapour, so all changes in weather and climate take place here. Temperature decreases by 1°C for every 165 m of height. It is the most important layer for all biological activity.
The tropopause separates the troposphere from the stratosphere. Its temperature is about −80°C over the equator and −45°C over the poles; temperature stays nearly constant here — hence the name (‘pause’).
5. Stratosphere, mesosphere, ionosphere and exosphere
| Layer | NCERT facts | Beyond NCERT |
|---|---|---|
| Stratosphere | Above the tropopause up to 50 km; contains the ozone layer, which absorbs UV radiation and shields life from intense, harmful energy | Temperature rises with height because ozone absorbs UV; air is calm and dry — good for long-haul flights in its lower part |
| Mesosphere | Up to 80 km; temperature falls again, to about −100°C at 80 km; top = mesopause | The coldest part of the atmosphere; most meteors burn up here |
| Ionosphere (thermosphere) | 80–400 km, above the mesopause; electrically charged ions; reflects radio waves transmitted from the earth; temperature increases with height | Auroras (northern and southern lights) glow here; the International Space Station orbits at about 400 km |
| Exosphere | Uppermost layer above the thermosphere; very little known; extremely rarefied; merges gradually with outer space | Many satellites orbit here |
6. Elements of weather and climate
- Temperature — Chapter 8
- Pressure and winds — Chapter 9
- Humidity, clouds and precipitation — Chapter 10
NCERT calls these the main elements of the atmosphere that are subject to change and influence human life. Weather is their state at a place over a short time; climate is their average pattern over a long period (usually 30 years or more — Beyond NCERT).
NCERT exercise — answer outlines
The five multiple-choice questions are in the Self-check below. Try each written question yourself first, then open the outline to compare.
2(i) What do you understand by atmosphere? (30 words)
2(ii) What are the elements of weather and climate? (30 words)
2(iii) Describe the composition of atmosphere. (30 words)
2(iv) Why is troposphere the most important of all the layers of the atmosphere? (30 words)
3(i) Describe the composition of the atmosphere. (150 words)
Gases: nitrogen ~78%, oxygen ~21%, argon ~0.93% (standard values); CO₂ — small but vital: transparent to sunlight, opaque to outgoing heat → greenhouse effect; rising with fossil fuels. Ozone (10–50 km) absorbs UV. Oxygen negligible at 120 km; CO₂ and vapour only up to 90 km.
Water vapour: variable; up to 4% in wet tropics, under 1% in deserts and poles; decreases with height and towards the poles; absorbs insolation and keeps the earth's heat — a blanket; affects stability of air.
Dust: sea salt, soil, soot, ash, pollen, meteor dust; mostly in lower layers; more over subtropical and temperate regions (dry winds); act as hygroscopic nuclei for clouds.
Conclude: minor constituents control weather and life.
3(ii) Draw a suitable diagram for the structure of the atmosphere, label it and describe it. (150 words)
Troposphere: average 13 km (8 km poles, 18 km equator — convection); temperature falls 1°C per 165 m; all weather.
Tropopause: constant temperature; −80°C equator, −45°C poles.
Stratosphere: to 50 km; ozone absorbs UV; temperature rises.
Mesosphere: to 80 km; temperature falls to −100°C; mesopause on top.
Ionosphere: 80–400 km; ions reflect radio waves; temperature rises.
Exosphere: rarefied, merges with space.
Conclude: layers are defined by temperature trends; geographers focus on the first two.
What to remember
Numbers
One-liners
- CO₂: transparent to incoming, opaque to outgoing radiation.
- Ozone absorbs ultraviolet rays.
- Water vapour decreases with altitude and towards the poles.
- Dust and salt are hygroscopic nuclei for clouds.
- All weather happens in the troposphere.
- The troposphere is thickest at the equator because of convection.
- The ionosphere reflects radio waves.
- Geographers study mainly the troposphere and stratosphere.
Traps to avoid
- Nitrogen is the largest component of air, not oxygen.
- Ozone absorbs UV; CO₂ and water vapour absorb infrared (heat).
- Water vapour is least at the poles, not maximum.
- Dust is more in subtropical and temperate areas because of dry winds.
- The troposphere is thicker at the equator, yet the tropopause is colder there.
- Temperature rises in the stratosphere and thermosphere, falls in the troposphere and mesosphere.
- Radio reflection is due to ions, not ozone.
- NCERT's ‘1°C per 165 m’ differs slightly from the standard lapse rate of 6.5°C per km.
- Oxygen negligible at 120 km; CO₂ and vapour end at 90 km — don't swap.
How to strategise
Prelims — what UPSC asks
- Layer order and properties are perennial: the sequence of layers (1984, 1998), the ionosphere and radio waves (1996, 2011), why jets fly smoothly in the lower stratosphere (2011).
- NCERT sentences become statement pairs: troposphere thicker at the equator because of convection (2004, 2024); dust more in subtropical/temperate regions due to dry winds (2025 — Statement II was a twisted version); water vapour decreases with altitude and is not maximum at the poles (2024).
- Gases and radiation: the ozone layer's role (1982, 1986, 1987); CO₂ absorbs infrared (2012); moisture linked to latitude because warm air holds more vapour (2003).
- Watch the switch-words: increase/decrease, equator/poles, UV/infrared, transparent/opaque — UPSC traps live there.
Mains — where it appears and how to answer
- GS1: ‘Troposphere is a very significant atmospheric layer that determines weather processes. How?’ (2022). Use: height and why it varies (convection), water vapour and dust → clouds and rain, lapse rate → instability and convection, pressure and winds, jet streams near the tropopause, and the tropopause as a lid. Draw Figure 7.1.
- GS1/GS3 links: auroras and the ionosphere (2024 — Beyond NCERT box); greenhouse gases and ozone depletion connect to climate change (Chapter 11) and environment.
- Answer frame: define → composition/structure diagram → process (why) → significance for weather, life, communication → current issue (CO₂ rise, ozone recovery).
Self-check
Tap an option. NCERT's own exercise questions come first; the rest test the figures and common confusions.
1. Which one of the following gases constitutes the major portion of the atmosphere?
2. Atmospheric layer important for human beings is:
3. Sea salt, pollen, ash, smoke soot, fine soil — these are associated with:
4. Oxygen gas is in negligible quantity at the height of atmosphere:
5. Which one of the following gases is transparent to incoming solar radiation and opaque to outgoing terrestrial radiation?
6. Why is the troposphere thickest over the equator?
7. In which layer does temperature rise with height because of ozone absorbing ultraviolet rays?
UPSC questions from this chapter
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