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Metals and Non-metals
Start here: why this chapter matters
This is the third chapter of NCERT's Class 10 Science textbook (pages 37–57 of the 2026-27 reprint; the contents page and the PDF agree). It has five parts — physical properties (3.1), chemical properties of metals with the reactivity series (3.2), how metals and non-metals react, i.e. ionic compounds (3.3), occurrence and extraction of metals (3.4) and corrosion with its prevention and alloys (3.5) — with 14 activities, Figures 3.1–3.13 plus an unnumbered exercise figure and a photograph of the Delhi iron pillar, Tables 3.1–3.4, two ‘Do You Know?’ boxes and one more at the end, a ‘More to Know!’ box, five in-text question boxes, a summary and 16 exercise questions. As in the previous two chapters, every equation on this page is checked in the source — atoms and electric charge, including the electron half-equations.
- Neighbouring chapters: Chemical Reactions and Equations (Class 10, Chapter 1) gave displacement reactions (Activity 1.9 — the iron nail in copper sulphate), oxidation and reduction, and corrosion; Acids, Bases and Salts (Chapter 2) gave ‘acid + metal → salt + hydrogen’ and ‘metal oxides are basic’. The next chapter, Carbon and its Compounds, sets covalent bonds against this chapter's ionic ones. Geography gives the setting: Minerals and Energy Resources (Class 10 — ores and where they are mined) and Manufacturing Industries (Class 10 — iron and steel, aluminium smelting).
- Prelims — science: UPSC has asked about galvanising (1982, 1983, 1992, 1994), stainless steel (1980), ‘which is not an alloy’ (1984, 1989), solder (2006), 18-carat gold (2004), anodising (2000), sodium under kerosene (1998), coke in the blast furnace (1998), rusting and weight (1980), ionic compounds (2003) and heat conduction by copper (2001).
- GS3 — science, industry and environment: mining and metallurgy (roasting releases sulphur dioxide), the cost of corrosion and its prevention, recycling metals, and India's metallurgical heritage (the Delhi iron pillar — also GS1 culture).
| Word | What it means here |
|---|---|
| Malleable / ductile | Can be beaten into sheets / drawn into wires |
| Sonorous | Rings when struck — why school bells are metal |
| Allotrope | One of the different forms of the same element, e.g. diamond and graphite (carbon) |
| Amphoteric oxide | A metal oxide that reacts with both acids and bases to give salt and water (Al2O3, ZnO) |
| Reactivity (activity) series | Metals listed from most to least reactive, built from displacement experiments |
| Ionic (electrovalent) compound | Formed by transfer of electrons from a metal to a non-metal; made of ions, not molecules |
| Mineral / ore / gangue | Naturally occurring element or compound / a mineral rich enough to extract a metal profitably / the soil and sand mixed with it |
| Roasting / calcination | Strong heating of a sulphide ore in excess air / of a carbonate ore in limited air — both give the oxide |
| Metallurgy | Extracting metals from ores and refining them for use |
| Corrosion | Slow eating away of a metal surface by air, moisture and other chemicals (rust on iron) |
| Alloy | A homogeneous mixture of two or more metals, or a metal and a non-metal; an amalgam contains mercury |
- Metal ≠ ‘hard and shiny’. Sodium is soft enough to cut with a knife; mercury is a liquid; iodine, a non-metal, is shiny.
- Mineral ≠ ore. Every ore is a mineral, but a mineral is an ore only where the metal can be extracted profitably.
- Ionic ≠ covalent. Ionic bonds come from transfer of electrons (metal + non-metal, this chapter); covalent bonds from sharing (mostly non-metals, next chapter).
At a glance — the six ideas to carry away
- Physical properties: metals are lustrous, hard, malleable, ductile, sonorous and good conductors; non-metals are mostly dull, brittle and poor conductors. Exceptions: mercury (liquid metal), bromine (liquid non-metal), soft Li/Na/K, lustrous iodine, conducting graphite, very hard diamond.
- With oxygen: metal + O2 → basic oxide; Al2O3 and ZnO are amphoteric (react with acids and bases). Na2O and K2O dissolve to give alkalis. Na and K are kept under kerosene; Mg, Al, Zn, Pb carry a protective oxide layer; Ag and Au do not react even when hot.
- With water: K, Na violently (H2 catches fire); Ca gently; Mg with hot water; Al, Fe, Zn only with steam; Pb, Cu, Ag, Au not at all. With dilute HCl: Mg > Al > Zn > Fe; copper no reaction. HNO3 gives no H2 (oxidising) except with Mg and Mn when very dilute. Aqua regia (HCl : HNO3 = 3 : 1) dissolves gold.
- Reactivity series: K > Na > Ca > Mg > Al > Zn > Fe > Pb > [H] > Cu > Hg > Ag > Au. A metal displaces any metal below it from its salt solution; metals above H displace hydrogen from dilute acids.
- Ionic compounds form by electron transfer: Na (2,8,1) → Na+; Cl (2,8,7) → Cl−. They are hard, brittle solids with high melting points (NaCl 1074 K; CaO 2850 K), soluble in water but not in kerosene or petrol, and conduct only when molten or dissolved.
- Metallurgy: ore → remove gangue → (low: heat alone; medium: roast sulphides in excess air or calcine carbonates in limited air, then reduce with carbon or Al — thermit; high: electrolysis of molten compounds) → electrolytic refining (anode impure, cathode pure, anode mud). Rust needs air and water; prevention by paint, grease, galvanising, chrome plating, anodising, alloys.
1. Physical properties: metals vs non-metals
NCERT tests metals — iron, copper, aluminium, magnesium, sodium, lead, zinc — in six short activities. Rubbed with sandpaper, each shows a shining surface: metallic lustre (Activity 3.1). Most are hard to cut, but sodium — handled with tongs and dried between filter paper — cuts with a knife (3.2). Hammering flattens them: malleability; gold and silver are the most malleable (3.3). Drawing into wires is ductility; gold is the most ductile — about 2 km of wire from one gram (3.4). A wire heated near its clamp soon melts the wax holding a pin at its far end, but the wire itself does not melt: metals are good conductors of heat with high melting points (3.5); silver and copper conduct heat best, lead and mercury comparatively poorly. A bulb in a circuit glows when a metal bridges the gap: metals conduct electricity (3.6) — which is why wires carry a PVC or rubber-like coat. Metals that ring when struck are sonorous.
Non-metals are fewer — carbon, sulphur, iodine, oxygen, hydrogen and so on — and are solids or gases; bromine is the one liquid. Repeating the tests with coal or graphite, sulphur and iodine (Activity 3.7) fills Table 3.1. The lesson: physical properties alone cannot sort elements. All metals except mercury are solids at room temperature; gallium and caesium melt on a palm; iodine is lustrous; carbon exists as allotropes — diamond, the hardest natural substance with very high melting and boiling points, and graphite, which conducts electricity; the alkali metals (lithium, sodium, potassium) are soft, with low densities and low melting points. Chemical properties classify more clearly.
| Sample (Table 3.1, expected) | Surface | Hardness | Malleable / ductile | Conducts electricity | Sonorous |
|---|---|---|---|---|---|
| Iron, copper, aluminium | lustrous when cleaned | hard | yes / yes | yes | yes |
| Magnesium | lustrous when cleaned | fairly hard | yes / yes | yes | yes |
| Sodium | lustrous when freshly cut | soft (knife cuts it) | — | yes | — |
| Carbon: coal / graphite | dull / greyish-shiny | brittle | no / no | coal no; graphite yes | no |
| Sulphur | dull yellow | brittle | no / no | no | no |
| Iodine | lustrous (an exception) | brittle | no / no | no | no |
- Most malleable: gold and silver; most ductile: gold. Best heat conductors: silver and copper; poor: lead and mercury.
- Mercury is the liquid metal; bromine the liquid non-metal. Gallium and caesium are solids that melt in the hand (low melting points), not liquids.
- Graphite conducts electricity; diamond, another form of the same carbon, does not (Beyond NCERT for diamond's conduction).
- A coated electric wire: the copper inside conducts; the PVC outside insulates for safety.
- Gallium melts at about 29.8 °C and caesium at about 28.4 °C, both below body temperature (about 37 °C) — hence ‘melts in the palm’.
- Carbon's other allotropes include fullerenes (C60) and graphene (a single layer of graphite) — the next chapter touches on them.
- Metalloids such as silicon and germanium sit between metals and non-metals; they are the semiconductors of electronics.
2. Metals with oxygen: basic and amphoteric oxides
In Activity 3.8, burnt magnesium ribbon leaves an ash that dissolves to a solution turning red litmus blue (basic), while the fumes of burning sulphur dissolve to a solution turning blue litmus red (acidic): 2Mg + O2 → 2MgO, MgO + H2O → Mg(OH)2; S + O2 → SO2, SO2 + H2O → H2SO3 (equations Beyond NCERT — the activity asks you to write them). Most non-metals give acidic oxides; most metals give basic oxides. In Activity 3.9 (teacher's help, eye protection), metals are held in a flame with tongs. Almost all form oxides — metal + oxygen → metal oxide: 2Cu + O2 → 2CuO (black copper(II) oxide); 4Al + 3O2 → 2Al2O3.
Amphoteric oxides. Metal oxides are basic, but aluminium oxide and zinc oxide react with both acids and bases to give salt and water: Al2O3 + 6HCl → 2AlCl3 + 3H2O; Al2O3 + 2NaOH → 2NaAlO2 + H2O (sodium aluminate). For zinc oxide (Beyond NCERT equations): ZnO + 2HCl → ZnCl2 + H2O; ZnO + 2NaOH → Na2ZnO2 + H2O. Most metal oxides are insoluble in water, but sodium and potassium oxides dissolve to give alkalis: Na2O(s) + H2O(l) → 2NaOH(aq); K2O(s) + H2O(l) → 2KOH(aq).
Different metals, different appetites. Potassium and sodium react so vigorously that they catch fire in the open, so they are kept under kerosene. At ordinary temperature magnesium, aluminium, zinc and lead carry a thin protective oxide layer that stops further oxidation. Iron does not burn on heating, but iron filings sprinkled into a flame burn vigorously. Copper does not burn but the hot metal is coated with black copper(II) oxide. Silver and gold do not react with oxygen even at high temperatures. Sodium is the most reactive of the samples, magnesium less so; burning cannot rank zinc, iron, copper and lead — that needs more reactions.
- Amphoteric = Al2O3 and ZnO in NCERT. They are metal oxides that also act as acids — not non-metal oxides.
- Sodium is stored under kerosene because it reacts with oxygen and moisture and can catch fire — not because it ‘melts in air’ (UPSC 1998).
- Aluminium is very reactive yet used for cooking pans: its oxide layer protects it (exercise 12c).
- Anodising thickens aluminium's own oxide; it does not coat aluminium with another metal (that would be plating).
- ‘Burning’ in NCERT is not the only test: iron filings burn in a flame although an iron block does not — surface area matters.
- Neutral oxides of non-metals — carbon monoxide (CO), nitrous oxide (N2O) — show neither acidic nor basic behaviour; that is why NCERT's summary says non-metal oxides are ‘acidic or neutral’.
- Flame colours: sodium compounds give a golden-yellow flame, potassium lilac, barium green, copper blue-green — the basis of fireworks colours (UPSC 1989, 2004 asked strontium and barium).
- The same oxide-layer idea is called passivation; chromium in stainless steel forms such a layer.
3. Metals with water and with acids
Water (Activity 3.10, teacher's help): metals react with water to give a metal oxide and hydrogen; a soluble oxide then gives a metal hydroxide. Potassium and sodium react violently with cold water; the reaction is so exothermic that the hydrogen catches fire: 2K(s) + 2H2O(l) → 2KOH(aq) + H2(g) + heat energy; 2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g) + heat energy. Calcium reacts less violently — the hydrogen does not ignite — and the metal starts floating because hydrogen bubbles cling to it: Ca(s) + 2H2O(l) → Ca(OH)2(aq) + H2(g). Magnesium does not react with cold water but does with hot water, giving magnesium hydroxide and hydrogen, and also floats (Mg + 2H2O → Mg(OH)2 + H2, equation Beyond NCERT). Aluminium, iron and zinc react only with steam, giving the oxide and hydrogen: 2Al(s) + 3H2O(g) → Al2O3(s) + 3H2(g); 3Fe(s) + 4H2O(g) → Fe3O4(s) + 4H2(g). Lead, copper, silver and gold do not react with water at all.
Dilute acids (Activity 3.11 — sodium and potassium are left out as too dangerous): samples in dilute hydrochloric acid, each with a thermometer. Bubbles form fastest with magnesium, which also gives the highest temperature; reactivity falls in the order Mg > Al > Zn > Fe; copper gives no bubbles and no temperature change — it does not react with dilute HCl. The equations (asked for in the activity): Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g); 2Al(s) + 6HCl(aq) → 2AlCl3(aq) + 3H2(g); Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g); Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g). Nitric acid is different: it is a strong oxidising agent, so it oxidises the hydrogen to water and is itself reduced to nitrogen oxides (N2O, NO, NO2); only magnesium and manganese give hydrogen with very dilute HNO3.
- Calcium and magnesium float because hydrogen bubbles stick to them — not because they are lighter than water in NCERT's explanation.
- Iron + steam gives Fe3O4, not Fe2O3; aluminium + steam gives Al2O3.
- Nitric acid gives no hydrogen with metals (except Mg and Mn with very dilute acid) — a favourite exception.
- Aqua regia is 3 HCl : 1 HNO3, both concentrated — not the reverse.
- With dilute acid the most reactive metal tested is magnesium (Na and K were never tried).
- In aqua regia, nitric acid oxidises gold while chloride ions from hydrochloric acid hold the gold in solution as a complex ion (chloroauric acid) — together they do what neither can alone.
- Lead stands just above hydrogen, but its reaction with dilute HCl soon stops because insoluble lead chloride coats the metal.
4. Displacement and the reactivity series
In Activity 3.12, a clean copper wire goes into iron sulphate solution and an iron nail into copper sulphate solution; after 20 minutes only the iron nail has reacted — it is coated reddish-brown with copper and the blue solution fades: Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s). So iron is more reactive than copper. Reactive metals displace less reactive metals from their compounds in solution or molten form: Metal A + salt solution of B → salt solution of A + metal B, if A is more reactive than B. Because not every metal reacts with oxygen, water or acids, displacement gives better evidence. From Activities 1.9 and 3.12 comes Table 3.2, the reactivity or activity series.
| Metal (page 46 puzzle) | Iron(II) sulphate | Copper(II) sulphate | Zinc sulphate | Silver nitrate | So it sits… |
|---|---|---|---|---|---|
| A | no reaction | displacement | — | — | between Fe and Cu |
| B | displacement | — | no reaction | — | between Zn and Fe |
| C | no reaction | no reaction | no reaction | displacement | between Cu and Ag |
| D | no reaction | no reaction | no reaction | no reaction | below Ag |
- Displacement needs the more reactive metal as the solid and the less reactive one in the salt: Fe + CuSO4 works, Cu + FeSO4 does not.
- Cu + AgNO3 does react (copper is above silver) — exercise 1(d); Al + MgCl2 does not (aluminium is below magnesium).
- [H] is not a metal; it is in the list only to show which metals release hydrogen from dilute acids.
- The colour change in the iron-nail tube is blue → pale green (iron(II) sulphate), not blue → colourless.
- The fuller series in higher classes is based on standard electrode potentials; lithium sits at the very top. NCERT's 13-entry list is enough for school and Prelims.
- Displacement is used industrially: copper is recovered from dilute leach solutions by passing them over scrap iron (‘cementation’).
5. Why metals react: electrons, ions and ionic bonds
Noble gases, with completely filled valence shells, show little chemical activity, so reactivity is explained as a tendency to attain a completely filled valence shell. Table 3.3 lists configurations: a sodium atom (2, 8, 1) loses its one M-shell electron, leaving a stable octet in the L shell; with 11 protons and now 10 electrons it becomes the sodium cation Na+: Na → Na+ + e−. A chlorine atom (2, 8, 7) gains one electron; with 17 protons and 18 electrons it becomes the chloride anion Cl−: Cl + e− → Cl−. The oppositely charged ions are held by strong electrostatic forces as sodium chloride — which exists not as molecules but as aggregates of ions. For magnesium chloride, Mg → Mg2+ + 2e−, and the two electrons go to two chlorine atoms, giving Mg2+ and 2Cl−. Compounds formed by transfer of electrons from a metal to a non-metal are ionic or electrovalent compounds.
| Type (Table 3.3) | Element | Atomic number | Electrons in K, L, M, N | To reach a full shell (our column) |
|---|---|---|---|---|
| Noble gas | Helium (He) | 2 | 2 | full outer shell — little activity |
| Noble gas | Neon (Ne) | 10 | 2, 8 | full outer shell — little activity |
| Noble gas | Argon (Ar) | 18 | 2, 8, 8 | full outer shell — little activity |
| Metal | Sodium (Na) | 11 | 2, 8, 1 | loses 1 → Na+ |
| Metal | Magnesium (Mg) | 12 | 2, 8, 2 | loses 2 → Mg2+ |
| Metal | Aluminium (Al) | 13 | 2, 8, 3 | loses 3 → Al3+ |
| Metal | Potassium (K) | 19 | 2, 8, 8, 1 | loses 1 → K+ |
| Metal | Calcium (Ca) | 20 | 2, 8, 8, 2 | loses 2 → Ca2+ |
| Non-metal | Nitrogen (N) | 7 | 2, 5 | gains 3 → N3− |
| Non-metal | Oxygen (O) | 8 | 2, 6 | gains 2 → O2− |
| Non-metal | Fluorine (F) | 9 | 2, 7 | gains 1 → F− |
| Non-metal | Phosphorus (P) | 15 | 2, 8, 5 | gains 3 → P3− |
| Non-metal | Sulphur (S) | 16 | 2, 8, 6 | gains 2 → S2− |
| Non-metal | Chlorine (Cl) | 17 | 2, 8, 7 | gains 1 → Cl− |
- Cation = positive (metals lose electrons); anion = negative (non-metals gain). Losing electrons makes an atom positive, not negative.
- The nucleus does not change: Na+ still has 11 protons; only the electron count changes.
- ‘NaCl molecule’ is wrong: an ionic solid is a lattice of ions.
- NCERT slip: page 47 prints the chloride ion as ‘C1–’ (with the digit one) — read Cl−.
- Ionic (transfer, metal + non-metal) vs covalent (sharing, non-metals): the next chapter.
- Loss of electrons is oxidation and gain is reduction (Class 11 definition) — so forming NaCl oxidises sodium and reduces chlorine, linking this section to Chapter 1's redox.
- The number of electrons an atom loses or gains is its valency in the ionic compound (Na 1, Mg 2, Al 3; Cl 1, O 2).
6. Properties of ionic compounds
In Activity 3.13, salts such as sodium chloride, potassium iodide and barium chloride are examined: their state, what happens when heated on a spatula in a flame (Figure 3.7), whether they dissolve in water, petrol and kerosene, and whether their solutions light a bulb (Figure 3.8). The general properties: (i) physical nature — solids, somewhat hard because of strong attraction between ions, generally brittle, breaking under pressure; (ii) high melting and boiling points — much energy is needed to break the inter-ionic attraction (Table 3.4); (iii) solubility — generally soluble in water, insoluble in kerosene and petrol; (iv) conduction — they conduct in solution and when molten, because the ions can move to the oppositely charged electrodes, but not as solids, where the rigid structure holds the ions in place.
| Ionic compound (Table 3.4) | Melting point (K) | Boiling point (K) | Melting point in °C (Beyond NCERT conversion) |
|---|---|---|---|
| NaCl | 1074 | 1686 | about 801 °C |
| LiCl | 887 | 1600 | about 614 °C |
| CaCl2 | 1045 | 1900 | about 772 °C |
| CaO | 2850 | 3120 | about 2577 °C |
| MgCl2 | 981 | 1685 | about 708 °C |
- Solid ionic compounds do not conduct; molten or dissolved ones do. (UPSC 2003: ‘ionic compounds in the solid state are good conductors’ — false.)
- Ionic compounds are hard but brittle — not malleable like metals.
- ‘Insoluble in kerosene and petrol’ is NCERT's statement; alcohol is not mentioned. Many ionic compounds dissolve poorly in alcohol, but some (e.g. calcium chloride) dissolve well — Beyond NCERT nuance behind UPSC 2003's statement 1.
- Table 3.4 is in kelvin; subtract 273 for °C (NaCl melts at 801 °C).
- Water dissolves ionic solids because its polar molecules surround and stabilise the separated ions (UPSC 1994 asked this as ‘high dipole moment’).
- Molten-salt conduction is exactly what electrolytic extraction (Section 8) exploits: molten NaCl conducts, and sodium collects at the cathode.
7. Where metals come from: minerals, ores and the route to a metal
The earth's crust is the main source of metals; seawater holds soluble salts such as sodium and magnesium chlorides. Naturally occurring elements or compounds are minerals; minerals with a high enough percentage of a metal to extract it profitably are ores. Metals at the bottom of the series — gold, silver, platinum, copper — occur free (copper and silver also as sulphide or oxide ores). Those at the top (K, Na, Ca, Mg, Al) are never found free. Those in the middle (Zn, Fe, Pb) occur mainly as oxides, sulphides or carbonates. Many ores are oxides because oxygen is very reactive and abundant. Mined ore carries gangue — soil, sand and other impurities — removed first by methods based on differences in physical or chemical properties (enrichment). Then the metal is extracted by a route chosen by its reactivity (Figure 3.9), and finally refined.
- All ores are minerals; not all minerals are ores — profitability decides.
- Gangue is the unwanted rock mixed with ore — removed before extraction; slag (Beyond NCERT) is what forms during smelting when a flux reacts with gangue.
- NCERT inconsistency: Figure 3.9 places Cu with carbon reduction; the text says copper occurs free and is got from Cu2S by heating alone. Safe exam line: copper is a low-reactivity metal, extracted from its sulphide ore by roasting/self-reduction; answer ‘reduction using carbon’ only if a question quotes Figure 3.9.
- Top-of-series metals: ‘never found free’ — K, Na, Ca, Mg, Al.
- Bauxite (aluminium), haematite and magnetite (iron), galena (lead), zinc blende and calamine (zinc), cinnabar (mercury — NCERT names it), copper glance (Cu2S), argentite (silver). UPSC matched ores to metals in 1980, 1983, 1985 and 1988 — those questions are tagged to the geography chapters.
- Concentration methods include gravity separation, froth flotation (for sulphide ores) and magnetic separation.
8. Extracting and refining metals
Low in the series: oxides of very unreactive metals are reduced by heating alone. Cinnabar (HgS), an ore of mercury, heated in air gives mercuric oxide, which on further heating gives mercury: 2HgS(s) + 3O2(g) —[heat]→ 2HgO(s) + 2SO2(g); 2HgO(s) —[heat]→ 2Hg(l) + O2(g). Copper from Cu2S, by heating in air: 2Cu2S + 3O2(g) —[heat]→ 2Cu2O(s) + 2SO2(g); 2Cu2O + Cu2S —[heat]→ 6Cu(s) + SO2(g).
Middle of the series (iron, zinc, lead, copper): usually sulphides or carbonates. A metal is easier to obtain from its oxide, so first: roasting — heating a sulphide ore strongly in excess air: 2ZnS(s) + 3O2(g) —[heat]→ 2ZnO(s) + 2SO2(g); calcination — heating a carbonate ore strongly in limited air: ZnCO3(s) —[heat]→ ZnO(s) + CO2(g). The oxide is then reduced, e.g. with carbon: ZnO(s) + C(s) → Zn(s) + CO(g). Obtaining a metal from its compounds is a reduction. Besides carbon (coke), highly reactive metals such as sodium, calcium and aluminium can be used as reducing agents, because they displace less reactive metals: 3MnO2(s) + 4Al(s) → 3Mn(l) + 2Al2O3(s) + heat — manganese dioxide is reduced, aluminium oxidised. These reactions are so exothermic that the metal comes out molten; iron(III) oxide with aluminium is the thermit reaction, used to join railway tracks and cracked machine parts: Fe2O3(s) + 2Al(s) → 2Fe(l) + Al2O3(s) + heat.
Top of the series: carbon cannot reduce the oxides of sodium, magnesium, calcium or aluminium, because these metals have more affinity for oxygen than carbon. They are obtained by electrolytic reduction: sodium, magnesium and calcium by electrolysis of their molten chlorides, the metal depositing at the cathode (negative) and chlorine at the anode (positive) — at the cathode Na+ + e− → Na, at the anode 2Cl− → Cl2 + 2e−. Aluminium is obtained by electrolytic reduction of aluminium oxide.
Refining. Metals from these processes are not very pure. The most widely used method is electrolytic refining — for copper, zinc, tin, nickel, silver, gold and others. The impure metal is the anode, a thin strip of pure metal the cathode, and a solution of the metal's salt the electrolyte. Current makes metal from the anode dissolve into the electrolyte and an equal amount of pure metal deposit on the cathode; soluble impurities stay in solution and insoluble impurities settle below the anode as anode mud. For copper (half-equations Beyond NCERT): anode Cu(s) → Cu2+(aq) + 2e−; cathode Cu2+(aq) + 2e− → Cu(s).
- Roasting = sulphide ore, excess air, gives SO2; calcination = carbonate ore, limited air, gives CO2. Both end in the metal oxide.
- In refining, the impure metal is the anode (+) and the pure strip the cathode (−) — reversing them is the commonest error.
- In electrolytic extraction, metal collects at the cathode and chlorine at the anode.
- In the thermit reaction aluminium is the reducing agent (it is oxidised); iron(III) oxide is reduced.
- Carbon fails for the top metals because those metals hold oxygen more strongly than carbon does.
- Valuable metals such as silver and gold often turn up in the anode mud when copper is refined (Beyond NCERT).
- In a blast furnace, coke burns as fuel and also makes the reducing agent: C + O2 → CO2; CO2 + C → 2CO; Fe2O3 + 3CO → 2Fe + 3CO2. Limestone is the flux that removes silica: CaCO3 —[heat]→ CaO + CO2, CaO + SiO2 → CaSiO3 (slag). So coke reduces and supplies heat; it does not remove silica and is not an oxidising agent (UPSC 1998).
- Aluminium is made by electrolysing alumina dissolved in molten cryolite (the Hall–Héroult process); overall 2Al2O3 —[electricity]→ 4Al + 3O2. It needs very large amounts of electricity — why aluminium smelters sit near cheap power.
- Molten NaCl electrolysis overall: 2NaCl(l) —[electricity]→ 2Na(l) + Cl2(g).
9. Corrosion and its prevention
From Chapter 1: silver turns black in air by reacting with sulphur compounds to form silver sulphide; copper reacts with moist carbon dioxide in air and gains a green coat of basic copper carbonate; iron in moist air acquires a brown, flaky coating of rust. In Activity 3.14, clean iron nails go into three corked tubes: A with ordinary water (air and water), B with boiled distilled water under about 1 mL of oil (water but no dissolved air), C with anhydrous calcium chloride (dry air). After a few days, only the nails in A rust: iron needs both air (oxygen) and water. Equations for the tarnish and the green coat (Beyond NCERT): 4Ag + 2H2S + O2 → 2Ag2S + 2H2O; 2Cu + H2O + CO2 + O2 → CuCO3·Cu(OH)2.
Prevention. Rusting is prevented by painting, oiling, greasing, galvanising, chrome plating, anodising or making alloys. Galvanisation coats steel and iron with a thin layer of zinc; the article stays protected even if the zinc coat is broken — NCERT asks you to reason why. Zinc is more reactive than iron, so where both are exposed, zinc reacts first (Zn → Zn2+ + 2e−) and the iron is spared.
- Corrosion is the general term; rusting is corrosion of iron only. Silver's black coat is silver sulphide; copper's green coat is basic copper carbonate.
- Rusting needs air and water together; tube B (no air) and tube C (no water) prove each is necessary.
- When iron rusts its mass increases — it gains oxygen and water (UPSC 1980).
- Galvanising = zinc; tinning = tin (food cans); chrome plating = chromium; anodising = thicker aluminium oxide. Galvanised iron is protected even when scratched; tin-plate is not.
- Food cans use tin, not zinc, because zinc is more reactive and would react with food acids (exercise 4).
- Rust is mainly hydrated iron(III) oxide, Fe2O3·xH2O; it is porous and flaky, so unlike aluminium's oxide it does not protect the metal beneath.
- Galvanising is done by dipping iron into molten zinc (hot-dip galvanising — UPSC 1992) or by electroplating zinc.
- Sacrificial protection extends the zinc idea: blocks of zinc or magnesium bolted to ship hulls and buried pipelines corrode instead of the steel. Cathodic protection is the general term.
- Salt water speeds rusting (dissolved ions help the electrochemical reaction) — why coastal and winter-road steel corrodes faster.
10. Alloys
Alloying is a very good way to improve a metal's properties. Iron is the most widely used metal but never used pure: pure iron is very soft and stretches easily when hot. With a small amount of carbon (about 0.05%) it becomes hard and strong; with nickel and chromium it becomes stainless steel, hard and rust-free. An alloy is a homogeneous mixture of two or more metals, or a metal and a non-metal, made by melting the primary metal, dissolving the others in definite proportions, and cooling. If one metal is mercury, the alloy is an amalgam. The electrical conductivity and melting point of an alloy are lower than those of the pure metals: brass (copper and zinc) and bronze (copper and tin) conduct less well than copper, which is why copper is used for circuits; solder (lead and tin) has a low melting point and is used to join electrical wires.
| Alloy (NCERT) | Made of | Property gained | Use |
|---|---|---|---|
| Steel | iron + a little carbon (about 0.05%, NCERT) | hard and strong | construction, tools |
| Stainless steel | iron + nickel + chromium | hard; does not rust | utensils, cutlery, surgical tools (uses Beyond NCERT) |
| Brass | copper + zinc | conducts less than copper | fittings, utensils (Beyond NCERT) |
| Bronze | copper + tin | conducts less than copper | statues, medals, bells (Beyond NCERT) |
| Solder | lead + tin | low melting point | joining electrical wires |
| Amalgam | mercury + another metal | — | dental fillings (Beyond NCERT) |
| 22-carat gold | 22 parts gold + 2 parts copper or silver | harder than 24-carat | jewellery in India |
- Brass = copper + zinc; bronze = copper + tin — the commonest swap. Solder = lead + tin (UPSC 2006).
- Zinc is an element, not an alloy (UPSC 1984, 1989 — ‘which is not an alloy: bronze, brass, steel, zinc’).
- Stainless steel: NCERT says iron + nickel and chromium; all steel also has carbon. UPSC 1980's answer ‘chromium and carbon’ is the only option with chromium — chromium is the essential rust-proofing element.
- Alloys have lower conductivity and melting point than their pure component metals (NCERT's general statement).
- 18 carat = 18 parts gold out of 24, i.e. 18 gold + 6 other, not 18% gold.
- NCERT wording slips: solder is used for soldering (joining at low temperature), not ‘welding’; and brass and bronze do conduct electricity — just less well than copper.
- Stainless steel contains at least about 10.5% chromium, which forms a thin, self-healing chromium oxide layer (passivation).
- The Delhi pillar dates from the Gupta period and carries an inscription of a king ‘Chandra’, usually identified with Chandragupta II. Studies attribute its rust resistance to a high phosphorus content in the wrought iron, which helps a thin protective film form, together with Delhi's relatively dry climate.
- South India's wootz crucible steel was famed in antiquity — a GS1 culture link.
- Mercury from amalgam use in small-scale gold mining is a major source of mercury pollution; the Minamata Convention on Mercury (adopted 2013, in force 2017) aims to curb it.
NCERT's in-text questions and activities — short answers
Short outlines in page order, for questions in the running text, the activities and the five ‘Questions’ boxes.
Page 37: Uses of metals and non-metals in daily life; the properties you used to sort them; how properties relate to uses.
Activities 3.1–3.2 (page 37): Appearance before and after cleaning? Can the metals be cut with a knife? What about sodium?
Activity 3.3 (page 38): What happens when the metals are hammered?
Activity 3.4 (page 38): List metals whose wires you have seen.
Page 38: Which metals are used for cooking vessels, and why?
Activity 3.5 (page 38): What do you observe after some time? Does the wire melt?
Activity 3.6 (page 39): Does the bulb glow? What does this indicate?
Page 39: Why are electric wires coated with PVC or a rubber-like material?
Page 39: Why are school bells made of metals?
Activity 3.7 (page 39): Repeat the tests on carbon, sulphur and iodine; fill Table 3.1.
Activity 3.8 (page 40): Is the product of burning magnesium acidic or basic? Of burning sulphur? Write equations.
Page 40, Q1: Give an example of a metal which (i) is liquid at room temperature (ii) can be easily cut with a knife (iii) is the best conductor of heat (iv) is a poor conductor of heat.
Page 40, Q2: Explain malleable and ductile.
Activity 3.9 (page 41): Which metals burn easily, with what flame, how does the surface look, what is the order of reactivity, and are the products soluble?
Page 41: Recall how copper oxide reacts with hydrochloric acid.
Activity 3.10 (page 42): Which metals react with cold water, produce fire, start floating; which react with hot water, steam, or not at all? Order of reactivity?
Activity 3.11 (page 44): Which metals reacted vigorously with dilute HCl; which gave the highest temperature; order; equations.
Activity 3.12 (pages 44–45): In which tube did a reaction occur, how do you know, what is the equation and the type? Which is more reactive, copper or iron?
Page 46, Q1: Why is sodium kept immersed in kerosene oil?
Page 46, Q2: Equations for (i) iron with steam (ii) calcium and potassium with water.
(ii) Ca(s) + 2H2O(l) → Ca(OH)2(aq) + H2(g); 2K(s) + 2H2O(l) → 2KOH(aq) + H2(g) + heat energy
Page 46, Q3: Metals A–D in four salt solutions (table). (i) Most reactive? (ii) B in copper(II) sulphate? (iii) Order of decreasing reactivity?
Page 46, Q4: Which gas is produced when dilute HCl is added to a reactive metal? Write the reaction of iron with dilute H₂SO₄.
Page 46, Q5: What would you observe when zinc is added to iron(II) sulphate? Write the reaction.
Page 48: Name the cation and anion in MgCl₂.
Activity 3.13 (page 48): State of the salts; do they melt or colour the flame; solubility in water, petrol, kerosene; conductivity; nature?
Page 49, Q1: (i) Electron-dot structures of sodium, oxygen and magnesium. (ii) Show the formation of Na₂O and MgO by electron transfer. (iii) Name the ions.
Page 49, Q2: Why do ionic compounds have high melting points?
Page 52: In 3MnO₂ + 4Al → 3Mn + 2Al₂O₃, which substance is oxidised and which reduced?
Page 53, Q1: Define (i) mineral (ii) ore (iii) gangue.
Page 53, Q2: Name two metals found in nature in the free state.
Page 53, Q3: What chemical process is used for obtaining a metal from its oxide?
Activity 3.14 (page 53): What does this tell us about the conditions under which iron rusts?
Page 54: Galvanised articles are protected even if the zinc coat is broken. Reason it out.
Page 55, Q1: Oxides of zinc, magnesium and copper heated with the metals zinc, magnesium and copper — where does displacement occur?
Page 55, Q2: Which metals do not corrode easily?
Page 55, Q3: What are alloys?
NCERT exercise — answer outlines
1. Which pair will give a displacement reaction? (a) NaCl solution and copper (b) MgCl₂ solution and aluminium (c) FeSO₄ solution and silver (d) AgNO₃ solution and copper.
2. Which method is suitable for preventing an iron frying pan from rusting? (a) grease (b) paint (c) a coating of zinc (d) all of the above.
3. An element reacts with oxygen to give a compound with a high melting point, also soluble in water. The element is likely to be (a) calcium (b) carbon (c) silicon (d) iron.
4. Food cans are coated with tin and not zinc because (a) zinc is costlier (b) zinc has a higher melting point (c) zinc is more reactive than tin (d) zinc is less reactive than tin.
5. With a hammer, a battery, a bulb, wires and a switch: (a) how would you distinguish metals from non-metals? (b) Assess the usefulness of these tests.
6. What are amphoteric oxides? Give two examples.
7. Name two metals which will displace hydrogen from dilute acids, and two which will not.
8. In the electrolytic refining of a metal M, what would you take as the anode, the cathode and the electrolyte?
9. Pratyush heated sulphur and collected the gas. (a) Its action on (i) dry litmus (ii) moist litmus? (b) Balanced equation.
10. State two ways to prevent the rusting of iron.
11. What type of oxides are formed when non-metals combine with oxygen?
12. Give reasons: (a) Pt, Au, Ag are used for jewellery (b) Na, K, Li are stored under oil (c) aluminium, though highly reactive, is used for cooking utensils (d) carbonate and sulphide ores are converted into oxides during extraction.
13. Why do lemon or tamarind juice clean tarnished copper vessels?
14. Differentiate between metals and non-metals on the basis of chemical properties.
15. A fake goldsmith dipped gold bangles in a solution; they sparkled but lost much weight. What was the solution?
16. Why is copper used to make hot-water tanks and not steel?
What to remember
Numbers
One-liners
- Metals: lustrous, malleable, ductile, sonorous, good conductors; mercury is the only liquid metal, bromine the only liquid non-metal.
- Iodine is a lustrous non-metal; graphite conducts; diamond is the hardest natural substance.
- Metal oxides are basic; Al2O3 and ZnO are amphoteric; non-metal oxides are acidic or neutral.
- Na and K are kept under kerosene; Mg, Al, Zn, Pb carry protective oxide layers; Ag and Au do not react with oxygen.
- K, Na: violent with cold water · Ca: gentle · Mg: hot water · Al, Fe, Zn: steam · Pb, Cu, Ag, Au: none.
- Nitric acid gives no hydrogen (oxidising) — except Mg and Mn with very dilute acid.
- A metal displaces any metal below it in the series from its salt solution.
- Ionic compounds: transfer of electrons; hard, brittle, high-melting, water-soluble, conduct when molten or dissolved.
- Roasting: sulphide, excess air · calcination: carbonate, limited air · then reduce the oxide.
- Thermit: Fe2O3 + 2Al → 2Fe + Al2O3 — joins railway tracks.
- Electrolytic refining: impure anode, pure cathode, metal-salt electrolyte, anode mud.
- Rusting needs air and water; galvanising (zinc) protects even when scratched.
- Brass = Cu + Zn · bronze = Cu + Sn · solder = Pb + Sn · stainless steel = Fe + Ni + Cr · amalgam contains Hg.
Traps to avoid
- Brass is copper + zinc; bronze is copper + tin — not the reverse.
- Roasting needs excess air (sulphide ores); calcination needs limited air (carbonate ores).
- In refining the impure metal is the anode; in extraction by electrolysis the metal collects at the cathode.
- Sodium is kept in kerosene because it reacts with air and moisture — not because it melts in air.
- Solid ionic compounds do not conduct; molten or dissolved ones do.
- Aqua regia is 3 HCl : 1 HNO3; neither acid alone dissolves gold.
- Food cans: tin, not zinc — zinc is more reactive. Galvanised iron: zinc protects even when scratched; tin does not.
- Iron + steam gives Fe3O4, not Fe2O3.
- 18 carat = 18 parts gold + 6 parts other metals (75%), not 18% gold.
- NCERT slips: Figure 3.9 puts Cu with carbon reduction while the text gets Cu by heating alone; ‘C1–’ for Cl−; solder ‘welding’ for soldering; the summary's non-metal hydrides are not taught in the body.
How to strategise
Prelims — what UPSC asks
- Corrosion and galvanising are UPSC's favourite part: galvanising = zinc coating (1982, 1992, 1994); galvanised pipes resist rust because zinc oxidises more readily than iron (1983); rusting increases weight (1980); anodising deposits aluminium oxide (2000).
- Alloys: stainless steel (1980), ‘which is not an alloy’ — zinc (1984, 1989), 18-carat gold (2004), solder = lead + tin (2006). Learn composition and the reason each alloy is used.
- Reactivity and extraction: sodium under kerosene, with ‘melts in air’ as a false reason (1998); coke as reducing agent and fuel in the blast furnace (1998). Ionic compounds: solids do not conduct (2003). Heat conduction: copper feels hotter than glass (2001).
- Likely next: amphoteric oxides, aqua regia, the thermit reaction, roasting vs calcination, anode mud, nitric acid and hydrogen, the iron pillar, liquid and low-melting metals. Ore names (bauxite, haematite, galena) come from the geography chapters.
- Answer-key note (2001, copper vs glass): the stored key is (c) ‘A is true but R is false’. The assertion is true — copper conducts heat far better, so it delivers heat to the skin faster. But the reason, ‘the density of copper is more than that of glass’, is also true (copper about 8.9 g/cm³, glass about 2.5 g/cm³); it simply does not explain the assertion. The correct option is (b) both true, R not the correct explanation; treat the stored key as likely wrong.
- Answer-key note (2003, ionic compounds): statement 2 is plainly false (solid ionic compounds do not conduct). Statement 1, ‘insoluble in alcohol’, is a textbook generalisation — NCERT itself says kerosene and petrol — and some ionic salts do dissolve in alcohol. The stored key (a) ‘only 1’ stands as the best available option; treat the question as slightly flawed rather than the key as wrong.
Mains — where it appears and how to answer
- No GS Mains question in the bank so far is built on this chapter's core content. It supplies the science for GS3 answers on mining and metallurgy pollution (sulphur dioxide from roasting sulphide ores, heavy metals in slag — Beyond NCERT), corrosion and infrastructure maintenance, metal recycling and critical minerals, and for GS1 notes on India's metallurgical heritage (the Delhi iron pillar).
- Answer frame: process (one balanced equation or a reactivity-series line) → why it matters (economy, safety, environment) → prevention or control (coatings, alloys, emission scrubbing, recycling) → a line on policy, attributed.
- A small sketch — the reactivity ladder with extraction bands, or the galvanised-vs-tin-plate panel — fits in a 150-word answer.
Self-check
Tap an option. NCERT's own exercise questions come first; the rest test the figures and common confusions.
1. Which non-metal is a good conductor of electricity?
2. Which pair consists of amphoteric oxides?
3. An iron nail is placed in copper sulphate solution. What is seen after 20 minutes?
4. Which statement about ionic compounds is correct?
5. Heating a carbonate ore strongly in limited air to convert it into the oxide is called:
6. In the electrolytic refining of copper, the anode is:
7. Galvanised iron stays protected even when the coating is scratched because:
8. Bronze is an alloy of:
UPSC questions from this chapter
Open any question to attempt it in the Question bank — your attempt is saved to your progress.